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Beilstein J. Org. Chem. 2014, 10, 1290–1298, doi:10.3762/bjoc.10.130
Graphical Abstract
Scheme 1: Synthesis of TETs 1 and 2 and TATs 3 and 4.
Scheme 2: Synthesis of triptycenetripropiolic acid (TPA) 5 and 6.
Scheme 3: Synthesis of triphosphinotriptycenes (TPT) 7 and 8.
Figure 1: Nuclease activities of the triptycene derivatives 1–8. Agarose gel (top) shows results of the incub...
Figure 2: Effect of triptycene derivatives on the restriction endonuclease activity of HindIII and BamHI enzy...
Figure 3: (A) Oligomer duplex sequence that was used to study the effect of triptycene derivatives on the aba...
Figure 4: UV–vis spectra showing the hyperchromic effect after addition of ctDNA (20 μM) to 5 and 6 (80 μM).
Figure 5: UV–vis absorption spectra of (A) 2,6,14-trisubstituted triptycene derivatives 1, 3, 5 and 7 in DMSO...